Who would be more perfect for this metallic effect other than the Iron Man actor, Robert Downey Jr. Take a look at the 'before' and 'after' image below...so you'll have an idea of what I'm talking about.
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1. Naturally, you should start by opening your image in Photoshop.
2. Next, duplicate the image. Set the duplicate image layer to Overlay.
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3. With the duplicate image layer selected, go to Filter > Other > High Pass. Our goal here is to sharpen the image a little bit, so you can see some details on the skin tone. If you already have a high resolution image, no need to set the radius too high. Mine is set to 5.
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4. Now go to Image > Mode > Grayscale. If a message appear asking you to merge the layer, don't panic, just click 'Merge'.
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5. Next, go to Image > Mode > Duotone. Select Quadtone on the Type dropdown menu. Then, click the 'Load' button on the right.
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A window will open, select PANTONE(R) QUADTONES folder. And select the file Bl 541 513 5773 and click Load. You'll have something like below and click OK.
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6. Now, change the mode back to RGB. Go to Image > Mode > RGB Color.
7. Duplicate the image. And set the duplicate layer to 'Color Burn'. Set the opacity to 20%.
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8. We're gonna add some adjustment layers to amplify the effect. Go to Layer > New Adjustment Layer > Curves. Make an S-shape curve like the image below. The steep of your curve is up to you, whatever looks good on your image.
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9. Now go to Layer > New Adjustment Layer > Level. Adjust the level as follows.
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And we're done. You got yourself one explosive metallic portrait.
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